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Maria Holic Vol 6 by Minari Endou. A Yuri manga rated Older Teen, published in English by Tokyopop.
Kanako Miyamae breaks out in hives whenever a man touches her, so she transfers to an all-girls Catholic school hoping to find true love. Instead she discovers that the angelic, beautiful Mariya is actually a sadistic boy in disguise, and he's not about to let her reveal his secret.
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